|United States Patent||5,336,828|
|Malhotra, et. al.||Aug. 9, 1994|
|Inventors:||Malhotra; Ripudaman (San Carlos, CA); Tse; Doris S. (San Jose, CA); McMillen; Donald F. (Menlo Park, CA).|
|Assignee:||SRI International (Menlo Park, CA).|
|Filed:||Mar. 3, 1993|
|Intl. Cl.:||C07C 5/327;|
|U.S. Cl.:||585/654.; 585/658.;|
|Field of Search:||654;658 |
Bae, Y. K., et al., "Production, Characterization, and Deposition of Carbon Clusters", Symposium on Clusters and Cluster Assembled Materials: Special Session on Buckminsterfullerene, Boston, Mass., Nov. 29, 1990, published in The Proceedings of the 1990 Meeting of the MRS Society, pp. 1-9.
Kratschmer, W., et al., "Solid C(60) : A New Form of Carbon" Nature, vol. 347, Sep. 27, 1990, pp. 354-357.
A process is described for carrying out the dehydrogenation or hydrogenation, including hydrogenolysis, of a hydrocarbon in the presence of one or more soluble fullerene catalysts which have been dissolved in the hydrocarbon (when the hydrocarbon is a liquid capable of dissolving the fullerene catalyst) or dissolved in a solvent which is also a solvent for the hydrocarbon (when the hydrocarbon either is not a liquid or is not a liquid which is a solvent for the fullerene catalyst). The use of a liquid catalyst, i.e., a dissolved fullerene catalyst, inhibits coking reactions to thereby inhibit formation of coke on a solid catalyst or catalyst support by elimination of nucleation points or growth regions for such coke formation.